The Messages beta is now available and full-screen mode is a great way to use the application. However, you can’t see your buddy list in full-screen mode. However, there is a trick. Here is how you can see your buddy list window while in full-screen mode.
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Open Messages.
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Close your buddy list window.
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Click the full-screen icon on your main Messages window.
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Choose Window > Buddies (or CMD 1)
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Enjoy.